Polymer of Intrinsic Microporosity Induces Host-Guest Substrate Selectivity in Heterogeneous 4-Benzoyloxy-TEMPO-Catalysed Alcohol Oxidations
نویسندگان
چکیده
منابع مشابه
Supercritical carbon dioxide, a new medium for aerobic alcohol oxidations catalysed by copper-TEMPO.
The copper catalysed aerobic oxidation of selected alcohol substrates in supercritical carbon dioxide (scCO(2)), employing a range of simple copper(II) catalyst compounds, is here described. The copper acetate complex of polydimethylsiloxane (PDMS) functionalised pyridine (1), compound 2, has previously been synthesised and characterised by us and its solubility in scCO(2) demonstrated. Due to ...
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The characterisation, solubility testing, and alcohol adsorption studies of PIM-1 are reported. Techniques used for characterisation are N2 sorption and ATR-FTIR analysis. A number of solvents were tested for their ability to dissolve low molecular weight (~30 000 gmol -1 ), medium molecular weight (~60 000 gmol -1 ), and high molecular weight (~120 000 gmol -1 ) PIM-1.Results showed solubility...
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ژورنال
عنوان ژورنال: Electrocatalysis
سال: 2015
ISSN: 1868-2529,1868-5994
DOI: 10.1007/s12678-015-0284-8